safety data sheet - Adama

SAFETY DATA SHEET Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) Annex II

Agate EW Version 2

Revision Date 01-Feb-2015 Publish Date 01-Feb-2015

Product No FNG56797-44/4 R-18156 MCW-432 EW

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier

Agate EW Pure substance/mixture

Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Uses advised against

Fungicide No information available

1.3. Details of the supplier of the safety data sheet Supplier Address

ADAMA Agricultural Solutions UK Ltd Unit 15, Thatcham Buisness Village Colthrop Way, Thatcham Berkshire RG19 4LW, UK : 01635 860555 Fax: 01635 861555

For further information, please contact

Email address

[email protected]

1.4. Emergency telephone number Emergency Telephone

National Chemical Emergency Centre (UK): Tel: 01865 407333 (24 hours)

Section 2: HAZARD IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Category 4 - (H302) Acute toxicity - Oral Serious eye damage/eye irritation Category 2 - (H319) Category 2 - (H361d) Reproductive Toxicity Category 1 - (H400) Acute aquatic toxicity Category 1 - (H410) Hazardous to the Aquatic Environment - Chronic Hazard Classification according to Directive 67/548/EEC or 1999/45/EC Full text of R-phrases: see section 16

Xn;R22 - Xi;R36 - Repr. cat. 3;R63 - N;R50-53

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ 2.2. Label elements Labeling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms

Signal word

Warning

Hazard Statements

H302 - Harmful if swallowed H319 - Causes serious eye irritation H361d - Suspected of damaging the unborn child H410 - Very toxic to aquatic life with long lasting effects

Precautionary Statements

P102 - Keep out of reach of children P201 - Obtain special instructions before use P270 - Do not eat, drink or smoke when using this product P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P501 - Dispose of contents/ container to an approved waste disposal plant P280 - Wear protective gloves/protective clothing/eye protection/face protection***

EU Specific Hazard Statements

EUH401 - To avoid risks to human health and the environment, comply with the instructions for use EUH208 - Contains Propanoic acid, 2-hydroxy-, 2-ethylhexyl ester. May produce an allergic reaction*** SP1 - Do not contaminate water with the product or its container

Additional phrases for PPP 2.3. Other hazards No information available

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixture Chemical Name

Weight%

Tebuconazole

11-13.5

Prochloraz

22-27

Propanoic acid, 2-hydroxy-, 2-ethylhexyl ester

40-45

Sodium dioctyl sulphosuccinate

1.5-3

CAS No

EC No

Index No

Classification according Classification M-Factor REACH to Regulation (EC) No. according to Registration 1272/2008 [CLP] 67/548/EEC Number 107534-96-3 403-640-2*** 603-197-00-7 Acute Tox. 4 (H302) Xn; R22 Repr. 2 (H361d) Repr.Cat.3; Aquatic Acute 1 (H400) R63 M=1 Aquatic Chronic 1 (H410) N; R50-53 M=10 67747-09-5 266-994-5 613-128-00-2 Acute Tox. 4 (H302) Xn; R22 Aquatic Acute 1 (H400) N; R50-53 M=1 Aquatic Chronic 1 (H410) M=10 186817-80-1 Skin Irrit. 2 (H315) Xi;R36/38 Eye Irrit. 2 (H319) R43 Skin Sens. 1 (H317) 577-11-7

209-406-4

-

Skin Irrit. 2 (H315) Eye Dam. 1 (H318)

Xi; R38-R41

-

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ Full text of R-phrases: see section 16 Full text of H- and EUH-phrases: see section 16

Section 4: FIRST AID MEASURES 4.1. Description of first aid measures General advice

In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible). First aider: Pay attention to self-protection!.

Inhalation

Remove to fresh air. If breathing is irregular or stopped, administer artificial respiration. Call a physician.

Skin Contact

Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Consult a physician if necessary.

Eye contact

Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician.

Ingestion

Rinse mouth. Drink plenty of water. If symptoms persist, call a physician.

Self-protection of the first aider

Use personal protective equipment as required.

4.2. Most important symptoms and effects, both acute and delayed None known

Symptoms

4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically.

Note to physicians

Section 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media No information available. 5.2. Special hazards arising from the substance or mixture No specific hazard known. 5.3. Advice for firefighters In the event of fire, wear self-contained breathing apparatus In the event of fire and/or explosion do not breathe fumes

Section 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak.

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ For emergency responders Use personal protection recommended in Section 8. 6.2. Environmental precautions Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. 6.3. Methods and material for containment and cleaning up Methods for cleaning up Take up mechanically, placing in appropriate containers for disposal. 6.4. Reference to other sections Other Information See also section 8,13

Section 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Advice on safe handling Avoid contact with skin, eyes or clothing. Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local exhaust ventilation. General Hygiene Considerations Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. 7.2. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Keep in properly labeled containers. 7.3. Specific end use(s) Risk Management Methods (RMM) The information required is contained in this Material Safety Data Sheet.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters

Derived No Effect Level (DNEL)

No information available

Predicted No Effect Concentration (PNEC)

No information available.

8.2. Exposure controls Engineering Controls Personal protective equipment Eye/face protection Body Protection

Ensure adequate ventilation, especially in confined areas. Tight sealing safety goggles. Suitable protective clothing, Suitable protective clothing, Apron, Gloves made of plastic or rubber.

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ General Hygiene Considerations

Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended.

Environmental exposure controls

Do not allow into any sewer, on the ground or into any body of water.

Section 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Property Appearance Physical state Color Odor Odor threshold pH Melting point/freezing point °C Boiling point/boiling range °C Flash point °C Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapor pressure kPa Vapor density Relative density Solubility(ies) mg/l Partition Coefficient (n-octanol/water) Log Pow Autoignition temperature °C Decomposition temperature °C Kinematic viscosity mm2/s 40 °C Explosive properties Oxidizing properties 9.2. Other information Bulk density g/ml Surface tension mN/m

Values : : : : : : : : : : :

Liquid orange light brown No information available No data available 6.8-7.8 No data available No data available 154 Not Applicable Not Applicable No data available

: : : : :

No data available No data available 1.04-1.12 No data available

: : : : :

275 No data available 43.469 Not an explosive No data available

Method

Remarks

CIPAC MT 75.3

solution (1 %)

EEC A.9

EEC A.3

See Section 12 for more information

: : 35.6

EEC A.15 OECD 114

OECD 115 EEC A.5

Section 10: STABILITY AND REACTIVITY 10.1. Reactivity Not available. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions None under normal processing. 10.4. Conditions to avoid Heat, flames and sparks. 10.5. Incompatible materials

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ No information available 10.6. Hazardous decomposition products None under normal use conditions.

Section 11: TOXICOLOGY INFORMATION 11.1. Information on toxicological effects Acute toxicity Oral LD50 mg/kg Dermal LD50 mg/kg Inhalation LC50 mg/l/4h Skin corrosion/irritation Serious eye damage/eye irritation Respiratory/skin sensitization

Values : 2000 : >2000 : >5.35 : Non-irritating to the skin : Irritating to eyes : Not a skin sensitizer

Species Rat Rat Rat Rabbit Rabbit Guinea pig

Method OECD 423 OECD 402 OECD 403 OECD 404 OECD 405 OECD 406

Remarks

Chronic toxicity Germ cell mutagenicity Chemical Name

Tebuconazole Prochloraz

: Not classified : Not classified

Carcinogenicity

.

Chemical Name


: Not classified : Not classified

Reproductive toxicity . Chemical Name


: H361d - Suspected of damaging the unborn child : Not classified

STOT - single exposure Chemical Name Tebuconazole Prochloraz

: No information available : No data available

STOT - repeated exposure Chemical Name



Aspiration hazard Chemical Name



Section 12: ECOLOGICAL INFORMATION 12.1. Toxicity Aquatic toxicity Acute toxicity

Values

Species

Method

Remarks

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ Fish 96-hour LC50 mg/l

:

1.77

Crustacea 48-hour EC50 mg/l Algae 72-hour EC50 mg/l

: :

12 0.41

Other plants EC50 mg/l

:

Oncorhynchus mykiss Daphnia magna Selenastrum capricornutum

OECD 203

Static

OECD 202 OECD 201

Static

Terrestrial Toxicity Birds Oral LD50 mg/kg Chemical Name


: 1988 : 624

Bobwhite quail Bobwhite quail

US EPA 71-1

Bees Or alLD50 μg/ bee Chemical Name


: 83.05 : 684

Oral

12.2. Persistence and degradability Abiotic Degradation Water DT50 days

Values

Method

Remarks

Chemical Name


: 365 : 11.7

Soil DT50 days Chemical Name


: 34.8 : 223.62

Biodegradation Chemical Name


: Not readily biodegradable : Not readily biodegradable

OECD 301B OECD 301 D

12.3. Bioaccumulative potential Partition Coefficient (n-octanol/water) Log Pow

Values

Method

Remarks

EEC A.8

20-25 ° C

Method

Remarks

Chemical Name


: 3.7 : 4.3

Bioconcentration factor (BCF) Chemical Name


: 78 : 150-247

12.4. Mobility in soil Adsorption/Desorption

Values

Chemical Name


: 769 : 1222-8654

Koc Koc

12.5. Results of PBT and vPvB assessment The components in this formulation do not meet the criteria for classification as PBT or vPvB 12.6. Other adverse effects

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ No information available.

Section 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Waste from residues/unused products

Disposal should be in accordance with applicable regional, national and local laws and regulations.

Contaminated packaging

Improper disposal or reuse of this container may be dangerous and illegal.

Other Information

Waste codes should be assigned by the user based on the application for which the product was used.

Section 14: TRANSPORTATION INFORMATION IMDG/IMO 14.1 UN/ID No 14.2 Proper shipping name 14.3 14.4 14.5 14.6

Hazard Class Packing Group Marine pollutant Special precautions for user

RID/ADR 14.1 UN/ID No 14.2 Proper shipping name 14.3 14.4 14.5 14.6

Hazard Class Packing Group Environmental hazard Special precautions for user

ICAO/IATA 14.1 UN/ID No 14.2 Proper shipping name

3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( Tebuconazole, Prochloraz ) 9 III Yes



14.3 Hazard Class 14.4 Packing Group 14.5 Environmental hazard 14.6 Special precautions for user 14.7 Transport in bulk according to Not Applicable Annex II of MARPOL 73/78 and the IBC Code

Section 15: REGULATORY INFORMATION 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

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Agate EW - FNG56797-44/4 Revision Date 01-Feb-2015 _____________________________________________________________________________________________ 15.2. Chemical safety assessment A chemical safety assessment according to regulation (EC) No. 1907/2006 is not required. A risk assessment was performed according to directive (EC) No. 91/414 or according to regulation (EC) No. 1107/2009.

Section 16: OTHER INFORMATION Full text of R-phrases referred to under sections 2 and 3 R43 - May cause sensitization by skin contact R22 - Harmful if swallowed R63 - Possible risk of harm to the unborn child R36/38 - Irritating to eyes and skin R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment Full text of H-Statements referred to under sections 2 and 3 H302 - Harmful if swallowed H361d - Suspected of damaging the unborn child H411 - Toxic to aquatic life with long lasting effects H315 - Causes skin irritation H319 - Causes serious eye irritation H317 - May cause an allergic skin reaction H318 - Causes serious eye damage H400 - Very toxic to aquatic life H410 - Very toxic to aquatic life with long lasting effects Revision Note

*** - Change from previous version.

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet

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